Unlockable - Unlock new characters |
| Tachibana Ginchiyo | Battle on Wu Territory (Wu Forces) - Treasure Trove revealed by occupying the Open Field next to Eastern Fortress. |
| Oda Nobunaga | Battle of Chang Ban (Shu Forces) - Treasure Trove revealed by occupying the Northern Fortress. |
| Shima Sakon | Battle of Xia Pi (Wei Forces) - Treasure Trove revealed by occupying the Village. |
| Shimazu Yoshihiro | Battle for He Fei Castle (Wei Forces) - Treasure Trove revealed by occupying the Open Field on the southeast corner. |
| Toyotomi Hideyoshi | Battle of Guan Du (Wei Forces) - Treasure Trove revealed by occupying the Open Field on the northwest corner, above Wu Chao. |
| Oichi | Battle for He Fei Castle (Wu Forces) - Treasure Trove revealed by occupying the Open Field on the northeast corner. |
| Tokugawa Ieyasu | Invasion of Yi (Shu Forces) - Treasure Trove revealed by occupying the Open Field above Northwestern Fortress. |
| Maeda Keiji | Nan Zhong Campaign (Shu Forces) - Treasure Trove revealed by occupying the Open Field left from Northern Fortress. |
| Date Masamune | Battle of Jian Ye (Wei Forces) - Treasure Trove revealed by occupying the Open Field below Northwestern Depot. |
| Nene | Sixth Northern Campaign (Shu Forces) - Treasure Trove revealed by occupying the Open Field right from Northern Fortress. |
| Honda Tadakatsu | Sixth Northern Campaign (Shu Forces) - Treasure Trove revealed by occupying Northwestern Defense Base. |
| Mori Ranmaru | Battle for Wan Castle (Cao Cao Forces) - Treasure Trove revealed by occupying the Open Field left from Escape Point. |
| Akechi Mitsuhide | Jiao Zhi's Rescue (Sun Jian Forces) - Treasure Trove revealed by occupying the Open Field left from Southern Depot. |
| Takeda Shingen | Showdown at Chang Jiang (Wu Forces) - Treasure Trove revealed by occupying the Open Field above Southern Defense Base. |
| Azai Nagamasa | The Yellow Turban Rebellion (Yellow Turbans) - Treasure Trove revealed by occupying the Open Field two squares above Eastern Fortress. |
| Ishida Mitsunari | Jiao Zhi's Rescue (Nanman Forces) - Treasure Trove revealed by occupying the Open Field two squares to the right of Northern Defense Base. |
| Hattori Hanzo | Battle at the Yellow River (Yuan Shao Forces) - Treasure Trove revealed by occupying the Open Field below Southern Attack Base. |
| Lady Noh | Nan Zhong Campaign (Nanman Forces) - Treasure Trove revealed by occupying the Open Field two squares below NE Defense Base. |
| Miyamoto Musashi | Defeat him in Treasure Trove in Battle of He Fei, Wei side. Treasure Trove is north of north-western most Fortress. |
| Naoe Kanetsugu | Defeat him in Treasure Trove in Battle of Wu Zhang Plains, Wei Side. Treasure Trove is west of enemy main camp. |
| Diao Chan | Complete Si Shui Gate (Dong Zhou's side) 100% in free mode |
| Lu Bu | Complete battle of Xia Pi (Dong Zhou's side) 100% in free mode |
| Dong Zhuo | Complete Hu Lao Gate 100% in mosou mode |
| Zhang Jiao | Clear 100% on Yellow turban stage |
| Meng Huo | Clear 100% on Conquest of Nan Zhong stage |
| Pang Tong | Clear the last stage in the fouth column in Shu Mouso Mode |
| Liu Bei | Clear the last stage in the fouth column in Shu Mouso Mode |
| Yue Ying | Clear Zhauge Liang Mouso Mode |
| Jiang Wei | Clear Zhauge Liang Mouso Mode |
| Zhuge Liang | Clear Zhao Yun mosou mode |
| Huang Zhong | Clear Zhao Yun mosou mode |
| Guan Ping | Clear Zhao Yun mosou mode |
| Hideyoshi Toyotomi | Complete the Treasure Trove in Wei's Musou Mode on Battle of Xia Pi |
| Lubu(officer) | 100% completion on the whole Other story mode(10maps) |
| Da Qiao | Complete Mosou Mode with Sun Ce |
| Zou Ci | Get 100% complete on all Yuan Shaos story mode |
| Xiao Qiao | Complete Musou Mode with Zhou Yu |
| Zhou Tai | Beat Showdown at Chang Jiang with Zhou Yu |
| Xu Huang | Clear Musou Mode with any Wei Officer |
| Sun Ce | Clear Musou Mode with any Wu Officer |
| Gan Ning | Clear Musou Mode with any Wu Officer |
| Xiahou Yuan | Clear Musou Mode with any Wei Officer |
| Cao Ren | Clear Musou Mode with any Wei Officer |
| Wei Yan | Clear Musou Mode with any Shu Officer |
| Huang Gai | Clear Musou Mode with any Wu Officer |
| Yuan Shao | Finish Battle of Jie Qiao 100% |
